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Temperature dependence of thermal properties of Ag8In14Sb55Te23 phase-change memory materials

Identifieur interne : 000C95 ( Chine/Analysis ); précédent : 000C94; suivant : 000C96

Temperature dependence of thermal properties of Ag8In14Sb55Te23 phase-change memory materials

Auteurs : RBID : Pascal:09-0085160

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Abstract

The dependence of thermal properties of Ag8In14Sb55Te23 phase-change memory materials in crystalline and amorphous states on temperature was measured and analyzed. The results show that in the crystalline state, the thermal properties monotonically decrease with the temperature and present obvious crystalline semiconductor characteristics. The heat capacity, thermal diffusivity, and thermal conductivity decrease from 0.35 J/gK, 1.85 mm2/s, and 4.0 W/mK at 300 K to 0.025 J/gK, 1.475 mm2/s, and 0.25 W/mK at 600 K, respectively. In the amorphous state, while the dependence of thermal properties on temperature does not present significant changes, the materials retain the glass-like thermal characteristics. Within the temperature range from 320 K to 440 K, the heat capacity fluctuates between 0.27 J/g K and 0.075 J/g K, the thermal diffusivity basically maintains at 0.525 mm2/s, and the thermal conductivity decreases from 1.02 W/m K at 320 K to 0.2 W/mK at 440 K. Whether in the crystalline or amorphous state, Ag8In14Sb55Te23 are more thermally active than Ge2Sb2Te5, that is, the Ag8In14Sb55Te23 composites bear stronger thermal conduction and diffusion than the Ge2Sb2Te5 phase-change memory materials.

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Pascal:09-0085160

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<title xml:lang="en" level="a">Temperature dependence of thermal properties of Ag
<sub>8</sub>
In
<sub>14</sub>
Sb
<sub>55</sub>
Te
<sub>23</sub>
phase-change memory materials</title>
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<name>XINBING JIAO</name>
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<name>JINGSONG WEI</name>
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<div type="abstract" xml:lang="en">The dependence of thermal properties of Ag
<sub>8</sub>
In
<sub>14</sub>
Sb
<sub>55</sub>
Te
<sub>23</sub>
phase-change memory materials in crystalline and amorphous states on temperature was measured and analyzed. The results show that in the crystalline state, the thermal properties monotonically decrease with the temperature and present obvious crystalline semiconductor characteristics. The heat capacity, thermal diffusivity, and thermal conductivity decrease from 0.35 J/gK, 1.85 mm
<sup>2</sup>
/s, and 4.0 W/mK at 300 K to 0.025 J/gK, 1.475 mm
<sup>2</sup>
/s, and 0.25 W/mK at 600 K, respectively. In the amorphous state, while the dependence of thermal properties on temperature does not present significant changes, the materials retain the glass-like thermal characteristics. Within the temperature range from 320 K to 440 K, the heat capacity fluctuates between 0.27 J/g K and 0.075 J/g K, the thermal diffusivity basically maintains at 0.525 mm
<sup>2</sup>
/s, and the thermal conductivity decreases from 1.02 W/m K at 320 K to 0.2 W/mK at 440 K. Whether in the crystalline or amorphous state, Ag
<sub>8</sub>
In
<sub>14</sub>
Sb
<sub>55</sub>
Te
<sub>23</sub>
are more thermally active than Ge
<sub>2</sub>
Sb
<sub>2</sub>
Te
<sub>5</sub>
, that is, the Ag
<sub>8</sub>
In
<sub>14</sub>
Sb
<sub>55</sub>
Te
<sub>23</sub>
composites bear stronger thermal conduction and diffusion than the Ge
<sub>2</sub>
Sb
<sub>2</sub>
Te
<sub>5</sub>
phase-change memory materials.</div>
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<sub>8</sub>
In
<sub>14</sub>
Sb
<sub>55</sub>
Te
<sub>23</sub>
phase-change memory materials in crystalline and amorphous states on temperature was measured and analyzed. The results show that in the crystalline state, the thermal properties monotonically decrease with the temperature and present obvious crystalline semiconductor characteristics. The heat capacity, thermal diffusivity, and thermal conductivity decrease from 0.35 J/gK, 1.85 mm
<sup>2</sup>
/s, and 4.0 W/mK at 300 K to 0.025 J/gK, 1.475 mm
<sup>2</sup>
/s, and 0.25 W/mK at 600 K, respectively. In the amorphous state, while the dependence of thermal properties on temperature does not present significant changes, the materials retain the glass-like thermal characteristics. Within the temperature range from 320 K to 440 K, the heat capacity fluctuates between 0.27 J/g K and 0.075 J/g K, the thermal diffusivity basically maintains at 0.525 mm
<sup>2</sup>
/s, and the thermal conductivity decreases from 1.02 W/m K at 320 K to 0.2 W/mK at 440 K. Whether in the crystalline or amorphous state, Ag
<sub>8</sub>
In
<sub>14</sub>
Sb
<sub>55</sub>
Te
<sub>23</sub>
are more thermally active than Ge
<sub>2</sub>
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<sub>2</sub>
Te
<sub>5</sub>
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Sb
<sub>55</sub>
Te
<sub>23</sub>
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